Salty Matters

The Blog is written by me, John Warren. Once every three or four weeks or so I will post an article or two on an evaporite topic that has piqued my interest. On the Saltwork Publications webpage (under "the Works") there is a growing library of pdfs and epubs based on these blogs. These articles on the website have much higher resolution extractable graphics in than in the blog. There is also a link to this set of pdfs and epubs on the home page (www.saltworkconsultants.com).

Solikamsk sinkhole and potash ore

John Warren - Thursday, February 19, 2015

The Solikamsk-2 mine output currently accounts for a fifth of the Uralkali's potash capacity. The mine is one of Uralkali’s potash mines in the Kama district (western Urals) of Russia. The possible loss of the Solikamsk-2 mine in the near future may put upward pressure on the currently low world price of potash. Even if loss of production from the mine doesn't drive an increase in price, Uralkali as a company will continue to be profitable. All mines in Solikamsk basin benefit from low production costs, related to shallow ore depth. The collapse sinkhole is a classic example of what can happen if any salt or potash mine operates at a depth that is shallow enough to intersect the overlying  zone of active phreatic water crossflow.


In November 2014 the most recent example of an evaporite-related ground collapse or sinkhole, daylighted to the east of the Solikamsk-2 potash production site. It seems likely that halite-undersaturated waters, sourced from above, now flow into an area of the Solikamsk-2 workings that were no longer mined, but were still connected to the active extraction areas of the Solikamsk mine. Worldwide experience shows that flooding is difficult to control once a salt mass is breached. Increasing volumes of inflow waters into the mine workings will likely lead to the ultimate loss of the Solikamsk 2 mine, as it has in what are other now abandoned salt mines and solution brinefields across the world.

Recently the head of the Ural region's Mining Institute, Alexander Baryakh, was quoted as saying (Moscow Times Dec. 11 2014): ....."Based on our analysis and the world's experience in developing potassium mines, the risk of a negative scenario — the complete flooding on the mine — remains high. We are ready for this contingency, but we are doing everything possible to minimize related risks,"  adding that, "fortunately, the accident poses no danger to the residents of [the local town of] Solikamsk....”

When, in mid November, a stoping solution cavity above the abandoned section of the mine workings reached the surface, the resulting sinkhole diameter measured 30m by 40m. As of 6 February 2015, the at-surface sinkhole diameter had increased in size and measured 58 by 87 metres wide and was some 75 metres deep. Uralkali’s ongoing measurements show levels of brine inflow into the Solikamsk-2 mine continuously varied over this time frame. Between 11 December 2014 and 21 January 2015, the average brine inflow was around 200 cubic metres per hour. Between 22 January and 06 February 2015, the average brine inflow increased substantially, reaching approximately 820 cubic metres per hour. 

Accordingly, where underground equipment at Solikamsk 2 is not being used to mitigate the consequences of the collapse and water inflow, Uralkali has started to remove plant via the mine shaft. Three "Ural" continuous miners have already been dismantled and taken out. In line with their accident mitigation plan, Uralkali in a recent press release states: that the company continues to comprehensively monitor the situation both underground and at the surface; water inflows are monitored through brine level checks; groundwater levels are monitored by water monitoring wells and via the drilling of additional water monitoring wells currently in progress; gas levels are monitored around the sinkhole and in the mine; while the sinkhole is continuously monitored from a distance, using stationary cameras and air drones; and a seismologic network has been set up over the sinkhole area.

This latest collapse is one of a series of evaporite collapse dolines or sinkholes that have daylighted atop the mined regions in this part of Russia. Collapse cavities typically reach the surface some years after extraction operations below the collapse have ceased. For example, in 1995, a collapse sinkhole formed atop the Solikamsk-2 potash mine’s Verkhnekamsky deposit. The collapse on January 5th, 1995 resulted in a 4.7 magnitude seismic event on the Richter scale, with an associated initial 4.5 m of surface subsidence. Underground, the mine roof collapsed over an area measuring 600 m by 600 m. Across the period 1993 to 2005, several hundred earthquakes were recorded in the Berezniki-Solikamsk region with magnitudes varying from 2 to 5. These earthquakes were caused by collapsing underground tunnels of potash mines, mined out over the 70 continuous years of production. In October 2006, in order to prevent catastrophic outcomes of a sudden brine influx into the underground workings, Berezniki potash mine #1 was flooded by Uralkali. After that, three major sinkholes occurred in the region above the flooded workings.

On July 28th, 2007, a huge sinkhole appeared on the surface above the closed Berezniki mine #1, its creation likely aided by infiltration of undersaturated floodwaters water into the abandoned underground workings. At the surface this sinkhole had an initial size of 50 by 70 meters and was 15 meters deep. By November, 2008, the sinkhole had expanded into a crater measuring 437m by 323m and some 100 m deep.  The July 28th collapse released an estimated 900,000 cubic metres of gas (a mix of methane, hydrogen, carbon dioxide, carbon monoxide and other gases), which in turn led to gas explosions on the following day. Timely placement by the mine operators of a “significant volume” of backfill, prior to flooding, is credited with preventing further catastrophic collapses.

The mined potash ore level at both collapse sites (Solikamsk and Berezniki) is Middle Permian (Kungurian) in ag. The potash is halite-hosted and occurs in one of six evaporitic foreland sub-basins, extending from the Urals foreland to the Caspian basin. Sylvinite (potash) beneath the 1995 Verkhnekamsky collapse area was extracted from two to three halite-potash beds, with 10 to 16 metres of total extraction height. At that time the mine used a panel system of rooms and pillars under 200 to 400 m of overburden. Rooms were 13-16 m wide and pillars 11-14 m wide by 200 m long. Due to the relatively shallow nature of the Solikamsk and Berezniki potash ore levels, compared to other potash mines in the world, a “rule of thumb” used across the Upper Kama mining district is that surface subsidence typically reaches 50% of the subsurface excavation height around 48 months after excavation. 

The 1995 collapse event occurred 15 years after mining began, and 7 years after mining was completed in the area beneath the sinkhole. The delay before the main collapse doline surfaced implies there was a rigid bridging of overburden as a roof to the mine level. This is consistent with the uncommonly high release of seismic energy associated with the1995 collapse. The next largest collapses associated with published seismic measurements occurred in 1993 and 1997 with seismic magnitudes of 2.6 and 2.8, respectively.

An even earlier surface collapse occurred on July 25, 1986 atop a portion of the nearby 3rd Bereznki potash mine and is yet another case of a sinkhole forming atop a mine that was operating at relatively shallow depths. Potash extraction at Bereznki was active at depths of 235 and 425 m below surface. There, the targeted ore zone was overlain by a 100 m thick “salt complex” made up of halite and carnallite beds, overlain in turn by clays, carbonates, aquifers and sediments. Mining created “yield pillars,” with 5.3 m wide rooms, 3.8 m wide pillars and a 5.5 m mining height. After mining, conditions in mined-out areas were described as, “pillars crushed and roofs sagged.”

Observations of significant brine leakage into the 3rd Bereznki potash mine workings at a depth of 400m indicated a loss of hydraulic control as early as January of 1986. This was a prelude to the massive dissolution cavitation that was occurring in the 90 m interval of disturbed salt and clastics that overlay the potash level. Some 7 months later a large cavity formed in the sandstone/limestone overburden, which was nearly 200 m thick. In the mine it appeared the water inflow situation remained relatively stable, at least from January until July 1986. Failure of the mine head then occurred, the result of a cavity that had migrated vertically through more than 300m of limestones, mudstones and sandstones. 

Final cavity stoping was indicated by the near instantaneous appearance of a caprock sinkhole, which was 150 m deep and 40-80 m across and located at the top of a stoping breccia pipe or chimney of the same dimensions. Failure of this sequence began at 18:30 hours on July 25 with “clearly felt underground shocks” culminating with a final collapse at midnight, which was accompanied by an explosion with “flashes of light.” In the final stages of stoping by the rising solution pipe, before the sinkhole daylighted, it took only 12 days to migrate through the last 100 metres of mudstone. This very high rate of stoping was likely aided by structural weakness in a fracture zone along a local fold axis.

In all these cases of rapid sinkhole creation, the collapse occurred above what was formerly an active area of the mine  and took place some years after mining had ceased. In all cases, the ultimate cause of the size of the collapse was likely a combination of a significant cavity growth below what was a mechanically strong rock rock, likely a dolomite or a limestone bed. This unit had significant structural integrity and so allowed a solution cavity to expand prior to the ultimate brittle collapse of roof rock. Once collapse did occur, undersaturated groundwaters, sourced in the overburden, then reached the salt level in large volumes and further expanded the region of collapse. Likewise, once the upward stoping cavity reached the shallower unconsolidated sediment levels, the cavity's passage to the surface sped up so that it daylighted and expanded in a rapid fashion.  

Dissolving evaporites and solution dolines occur naturally in all parts of the world, wherever salt is within a few hundred metres of the landsurface, but mining of both salt and potash at depths shallower than 250-350 metres can exacerbate the speed and and intensity of what is an ongoing natural process of evaporite solution, surface collapse and sinkhole growth. While Uralkali's operations in this region continue to exploit a relatively shallow potash ore source, it will continue to supply the Company a relatively inexpensive product, but the company will have live with sinkholes breaking out above some areas of the mined region. That is, as long as Uralkali can continue to be a low cost supplier of potash, there will be likely be ongoing landsurface-stability problems. Some of the problems may not daylight until years after the extraction operation has ceased.


Recent Posts


Tags

Stebnik Potash climate control on salt evaporite intersalt Bathymodiolus childressi authigenic silica lunette Deep seafloor hypersaline anoxic lake SedEx oil gusher Magdalen's Road natural geohazard astrakanite lazurite salt trade salt ablation breccia Turkmenistan anthropogenic potash Zaragoza halophile jadarite perchlorate African rift valley lakes Hell Kettle deep seafloor hypersaline anoxic basin capillary zone 18O extrasalt ancient climate base metal silicified anhydrite nodules dissolution collapse doline basinwide evaporite Red Sea mine stability Lake Magadi trona Badenian GR log hydrohalite Gamma log halite-hosted cave Danakhil Depression, Afar carbon oxygen isotope cross plots York (Whitehall) Mine kainitite gas outburst Sumo Dallol saltpan doline Hyperarid bischofite Realmonte potash crocodile skin chert circum-Atlantic Salt Basins gas in salt Sulphate of potash anthropogenically enhanced salt dissolution waste storage in salt cavity MVT deposit knistersalz Evaporite-source rock association zeolite collapse doline potash epsomite Hadley cell: Lomagundi Event McArthur River Pb-Zn magadiite alkaline lake hydrothermal karst lithium battery evaporite-hydrocarbon association palygorskite potash ore sinjarite Thiotrphic symbionts salt leakage, dihedral angle, halite, halokinesis, salt flow, seal capacity CO2: albedo water on Mars CaCl2 brine tachyhydrite lithium carbonate Neoproterozoic Oxygenation Event Ripon anomalous salt zones stevensite HYC Pb-Zn Density log sulfate well blowout gassy salt Jefferson Island salt mine DHAL sedimentary copper gem rockburst methanogenesis NaSO4 salts mirabilite cryogenic salt organic matter vadose zone Messinian well logs in evaporites stable isotope dark salt namakier Dead Sea caves eolian transport hydrological indicator well log interpretation RHOB salt karst Platform evaporite auto-suture solar concentrator pans Pangaea Mesoproterozoic evaporite karst Paleoproterozoic Oxygenation Event Dead Sea karst collapse Atlantis II Deep venice halite hydrothermal potash potash ore price Koppen climate geohazard deep meteoric potash nitrogen evaporite-metal association carnallitite Lop Nur SOP saline clay sulphate lot's wife mass die-back 13C enrichment sulfur source rock sodium silicate bedded potash flowing salt Neutron Log vestimentiferan siboglinids hectorite sinkhole Lake Peigneur vanished evaporite North Pole Lop Nor Weeks Island salt mine endosymbiosis recurring slope lines (RSL) Ure Terrace Precambrian evaporites Catalayud sepiolite Belle Isle salt mine Schoenite Clayton Valley playa: H2S Warrawoona Group Mega-monsoon salt suture nuclear waste storage allo-suture Quaternary climate salt seal Corocoro copper brine lake edge blowout intrasalt nacholite salt periphery High Magadi beds Kara bogaz gol silica solubility supercontinent Archean salt tectonics carbon cycle Karabogazgol brine pan Ingebright Lake MOP causes of glaciation chert lapis lazuli DHAB subsidence basin snake-skin chert meta-evaporite Dead Sea saltworks Neoproterozoic 18O enrichment hydrogen Pilbara Crescent potash Lamellibrachia luymesi Ethiopia Proterozoic lithium brine Stebnyk potash 13C sulphur Salar de Atacama solikamsk 2 Muriate of potash Kalush Potash NPHI log Five Island salt dome trend evaporite dissolution black salt marine brine Deep water in modern-day Mars K2O from Gamma Log Boulby Mine salt mine dihedral angle brine evolution methanotrophic symbionts halotolerant gypsum dune Seepiophila jonesi halokinetic Musley potash freefight lake methane Great Salt Lake antarcticite Koeppen Climate mummifiction CO2 wireline log interpretation cauliflower chert Zabuye Lake Calyptogena ponderosa

Archive